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Charizard ex Special Illustration Rare (#199) Let's start with the undisputed king of the set

Mega Excadrill ex Ultra Rare #103/084 Ultra Rare #14

Thats because it includes multiple Characters with 5000 power or more

Pikachu Illustrator [PSA 10] Publication Date: 1998 Grading: PSA 10 Market Price: $16,500,000 Move over, Charizard the crown of the most expensive Pokmon card ever now belongs to a PSA 10 Pikachu Illustrator

Six As one half of the famed planeswalker duo Wrenn and Six, Six is a legendary 2/4 Treefolk for three mana with reach and the ability to recur lands straight into play from your graveyard when it attacks